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Angel (David Boreanaz) and Buffy (Sarah Michelle Gellar) on Buffy the Vampire Slayer. From their first meeting in a darkened alley, they set my TV set ablaze. The two of them engaged one another like no one else on the series. Although, I find it hard to believe that David could not have chemistry with anyone, given his recent well matched pairing on Bones. —Liz
Buffy [Sarah Michelle Gellar] and Spike [James Marsters] on Buffy the Vampire Slayer. The characters complimented each other (...)