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Sydney Bristow would kick Buffy’s ass. Buffy obviously has strength advantage but Syd is quicker, more resourceful and miles more intelligent. She’s more capable with weapons and is simply a tougher chick. Buffy would go down, especially if they were armed. Seriously Buffy is capable with a stake but Syd has an awesome aim - Buffy would have a bullet between her eyes in no time.
Syd wins.